HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Bromo-2-fluoro-3-nitrobenzene → 3-Bromo-2-fluoroaniline
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Bromo-2-fluoro-3-nitrobenzene | HCID 40427446 | — |
| Reactant | 2-Chloro-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzenamine | HCID 58164432 | — |
| Product | 3-Bromo-2-fluoroaniline | HCID 22341891 | — |
Reaction Steps
This material was prepared from 1-bromo-2-fluoro-3-nitrobenzene, following the procedure used for SM-9, step 2 (94%): LCMS (m/z) 189.9, tR=0.74 minute; 1H NMR (300 MHz, CDCl3) δ 3.81 (br s, 2H) 6.64-6.75 (m, 1H) 6.80 (t, J=8.2 Hz, 1H) 6.84-6.95 (m, 1H).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08859548B2 |
| Source dataset | uspto-grants-2014_10 |
| ORD ID | ord-014c26a3e16d4b729218ce3be0dfb9f2 |
| Source note | uspto-grants-2014_10 |