HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acetic Acid → 1,3-Diethyl 2-oxopropanedioate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acetic Acid | HCID 176 | — |
| Reactant | Diethyl Malonate | HCID 7761 | — |
| Reactant | Sodium Chlorite | HCID 23668197 | — |
| Product | 1,3-Diethyl 2-oxopropanedioate | HCID 69105 | — |
Reaction Steps
A reaction was performed similarly to Example 1 using 0.25 g (0.0016 mole) diethyl malonate, 0.95 mL (0.0166 mole) acetic acid, 1.71 g (0.0047 mole) of 25% sodium chlorite aqueous solution, and GC analysis was performed to give 88.1% GC total area value of diethyl ketomalonate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08859803B2 |
| Source dataset | uspto-grants-2014_10 |
| ORD ID | ord-9e0860ac526247d39efab180984643c7 |
| Source note | uspto-grants-2014_10 |