Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Benzyl Alcohol | HCID 244 | — |
| Reactant | Water | HCID 962 | — |
| Reactant | Sulfuric Acid | HCID 1118 | — |
| Reactant | Phenyl chloroformate | HCID 15891 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | Benzyl phenyl carbonate | HCID 11183772 | 99% |
Reaction Steps
Benzyl alcohol (10.8 g, 100.0 mol) was dissolved in 100 mL of CH2Cl2. The solution was cooled down to 0° C. and phenyl chloroformate (15.7 g, 100 mol) was slowly added dropwise. The solution was stirred at RT overnight. Addition of 100 mL of H2O was followed by 2× washes with 100 mL of 2M H2SO4 each time. The organic phase was separated off and dried over Na2SO4. The solvent was removed in vacuo to obtain a colorless liquid (22.5 g, 99%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US08865863B2 |
|---|
| Source dataset | uspto-grants-2014_10 |
|---|
| ORD ID | ord-4d93e95d433242799749fe36f4d3c69d |
|---|
| Source note | uspto-grants-2014_10 |
|---|
