Chloroform → HCID 15699040, compound

HRID 53956Notes

Reaction equation

HRID 53956 reaction equation
[CH3:1][C:2]1[CH:3]=[C:4]2[C:9](=[CH:10][CH:11]=1)[CH:8]=[C:7]([C:12]#[N:13])[CH:6]=[CH:5]2.[Br:14]N1C(=O)CCC1=O.C(Cl)(Cl)Cl>C(Cl)(Cl)(Cl)Cl>[Br:14][CH2:1][C:2]1[CH:3]=[C:4]2[C:9](=[CH:10][CH:11]=1)[CH:8]=[C:7]([C:12]#[N:13])[CH:6]=[CH:5]2

Participants

5

Reactant 3

HCID 6212ChloroformHCID 67184N-bromobutanimideHCID 156990366-Methylnaphthalene-2-carbonitrile

Product 1

HCID 15699040HCID 15699040, compoundYield 78.6%

Reagents, catalysts & solvents 1

HCID 5943Carbon TetrachlorideSolvent

Procedure

6.11 g of 6-methyl-2-naphthalenecarbonitrile was dissolved in 100 ml of carbon tetrachloride, and the solution was mixed with 6.63 g of N-bromosuccinimide and 30 mg of 2,2-azobis-iso-butylonitrile. After refluxing under heating for 4 hours, the resulting reaction solution was mixed with chloroform, washed with water, and then dried. By distilling off the solvent, 7.07 g of colorless 6-bromomethyl-2-naphthalenecarbonitrile was obtained.

Workup

  1. temperatureAfter refluxing
  2. temperatureunder heating for 4 hours
  3. customthe resulting reaction solution
  4. washwashed with water
  5. customdried
  6. distillationBy distilling off the solvent

Sources & evidence

ORD record
ord-329c52f978244614b2735cf0cab095b1
Source dataset
uspto-grants-1997_04
Patent number
US05620991

Reaction notes

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