HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Phenyl-2-butanol → 4-Methoxybenzyl alcohol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Phenyl-2-butanol | HCID 61302 | — |
| Reactant | alpha-Methyl-2-pyridinemethanol | HCID 86784 | — |
| Reactant | 2-Oxido-2-azoniatricyclo[3.3.1.03,7]nonane | HCID 101536640 | — |
| Product | 4-Methoxybenzyl alcohol | HCID 7738 | — |
Reaction Steps
2-(1-Hydroxyethyl)pyridine (76.8 mg, 0.624 mmol) was oxidized in the same manner as that described in Example 8, (a) (except that Nor-AZADO was used at 3 mol %, and the reaction was performed at room temperature) to obtain the objective compound (66.0 mg; yield, 87.4%). The spectrum data were found to be the same as those obtained in Example 6, (h).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08871981B2 |
| Source dataset | uspto-grants-2014_10 |
| ORD ID | ord-31220d8df9174332927d5f16647c901d |
| Source note | uspto-grants-2014_10 |