Potassium Permanganate → HCID 10953541, compound

HRID 542169Notes

Reaction equation

HRID 542169 reaction equation
[OH:1][CH2:2][CH:3]([CH3:9])[CH2:4][CH2:5][C:6]([OH:8])=[O:7].[Mn]([O-])(=O)(=O)=O.[K+]>>[O:1]=[CH:2][CH:3]([CH3:9])[CH2:4][CH2:5][C:6]([OH:8])=[O:7]

Participants

3

Reactant 2

HCID 516875Potassium PermanganateHCID 214216545-Hydroxy-4-methylpentanoic acid

Product 1

HCID 10953541HCID 10953541, compound

Procedure

1.00 g. (7.57 mmol) of 5-hydroxy isocaproic acid was oxidized with 0.82 g. (5.22 mmol) of potassium permanganate in an aqueous base according to the procedure of Carson, et al., Org. Syn. Col. Vol. 1, 241 (1941). The oily product contaminated with a minor amount of starting material was characterized by NMR and used without further purification.

Workup

  1. customused without further purification

Sources & evidence

ORD record
ord-3f42c4e7729e480aa43589aaefa43cb9
Source dataset
uspto-grants-1987_04
Patent number
US04656169

Reaction notes

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