HuagongsheHuagongshe Chemistry Print Report · For research reference only
Iodoform → 1-Oxo-1-(4-chlorophenyl)-3-iodo-2-propene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Iodoform | HCID 6374 | — |
| Reactant | (4-Chlorophenyl)(oxo)acetaldehyde | HCID 269588 | — |
| Catalyst | chromium(II) dichloride | HCID 10197677 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 1-Oxo-1-(4-chlorophenyl)-3-iodo-2-propene | HCID 54373096 | — |
Reaction Steps
This compound is prepared in a manner analogous to that of Step C of Example 4, using 6.7 grams (0.04 mole) of 4-chlorophenylglyoxal (prepared by the method of Kornblum et al., JACS, (1957), 79, 6562), 29.5 grams (0.24 mole) of anhydrous chromium(II) dichloride, and 31.5 grams (0.08 mole) of iodoform in 600 mL of tetrahydrofuran, yielding 1-oxo-1-(4-chlorophenyl)-3-iodo-2-propene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05622954 |
| Source dataset | uspto-grants-1997_04 |
| ORD ID | ord-96efb8b9fa07495b9c0fddd1bf2d549f |
| Source note | uspto-grants-1997_04 |