4-Methoxyphenol → Carbonic acid, methyl 2-methyl-2-propenyl ester

Participants

Reaction Steps

The reaction conditions of Example 37 are substantially repeated employing 3-chloro-2-methyl-l-propene (181.1 g, 2.0 moles), dimethyl carbonate (450.0 g, 5.0 moles), 30.0 g of DOWEX® MWA-1 beads and p-methoxyphenol (1.0 g, 0.08 mole). After 2 hours at 150° C., distillation gives 37.7 g (15.3 percent yield based on 3-chloro-2-methyl-1-propene) of methallyl methyl carbonate, b.p. 89° C.-90° C. (100 torr) and 1.2 g (0.7 percent yield based on 3-chloro-2-methyl-l-propene) of bis(2-methylallyl)carbonate, b.p. 87° C.-88° C. (17 torr).

Provenance & Evidence