HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzoyl Peroxide → 1-Bromo-3-(bromomethyl)-5-methoxybenzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzoyl Peroxide | HCID 7187 | — |
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | 1-Bromo-3-methoxy-5-methylbenzene | HCID 10679554 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | 1-Bromo-3-(bromomethyl)-5-methoxybenzene | HCID 12276449 | — |
Reaction Steps
A mixture of 5-bromo-3-methoxytoluene (20 g, 0.1 m), N-bromosuccinimide (17.8 g, 0.1 m) and dibenzoyl peroxide in carbon tetrachloride (200 ml) is heated to reflux and irradiated with a sunlamp. The mixture is cooled, filtered and concentrated in vacuo to give 5-bromo-3-methoxybenzyl bromide.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04659706 |
| Source dataset | uspto-grants-1987_04 |
| ORD ID | ord-a4d130a503364d3fa2710805bc0d4325 |
| Source note | uspto-grants-1987_04 |