HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Azide → alpha-D-Mannopyranosyl azide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Azide | HCID 33557 | — |
| Reactant | alpha-D-Mannopyranosyl fluoride | HCID 11412739 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | alpha-D-Mannopyranosyl azide | HCID 54011468 | — |
Reaction Steps
12 g of α-mannosyl fluoride were heated with 4.7 g of sodium azide in 100 ml of acetonitrile for 80 hours at the reflux temperature. After the mixture had been worked up as in Example 1, 10.3 g of a syrup containing 92% of α-azidomannose were obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04659810 |
| Source dataset | uspto-grants-1987_04 |
| ORD ID | ord-e3c12ccfc5864eada66a8e919e76edc9 |
| Source note | uspto-grants-1987_04 |