2-Propen-1-yl 1,1,1-trifluoromethanesulfonate → HCID 14324143, compound

HRID 543085Notes

Reaction equation

HRID 543085 reaction equation
[F:1][C:2]([F:11])([F:10])[S:3]([O:6][CH2:7][CH:8]=[CH2:9])(=[O:5])=[O:4].[CH3:12][O:13][C:14]1[C:15]([O:24][CH3:25])=[CH:16][C:17]2[Te:21][C:20]([CH3:22])=[N:19][C:18]=2[CH:23]=1>C(Cl)(Cl)(Cl)Cl.ClCCl>[F:1][C:2]([F:11])([F:10])[S:3]([O-:6])(=[O:5])=[O:4].[CH3:12][O:13][C:14]1[C:15]([O:24][CH3:25])=[CH:16][C:17]2[Te:21][C:20]([CH3:22])=[N+:19]([CH2:9][CH:8]=[CH2:7])[C:18]=2[CH:23]=1

Participants

5

Reactant 2

HCID 109322232-Propen-1-yl 1,1,1-trifluoromethanesulfonateHCID 139312085,6-Dimethoxy-2-methylbenzotellurazole

Product 1

HCID 14324143HCID 14324143, compound

Reagents, catalysts & solvents 2

HCID 5943Carbon TetrachlorideSolventHCID 6344DichloromethaneSolvent

Procedure

A dried solution of 2-propen-1-yl tri-fluoromethanesulfonate (0.002 mole) in carbon tetrachloride was added dropwise to a solution of 5,6-dimethoxy-2-methylbenzotellurazole (Example 19) (0.50 g, 0.0016 mole) in dichloromethane (25 ml) under a nitrogen atmosphere at room temperature. After the addition was complete, stirring was continued for 7 hours. The solid was isolated by filtration, washed with diethyl ether, and dried at room temperature under vacuum. Yield 0.38 g. A mass spectrogram of the compound was in agreement with that expected for the structural formula.

Workup

  1. additionAfter the addition
  2. customThe solid was isolated by filtration
  3. washwashed with diethyl ether
  4. customdried at room temperature under vacuum

Sources & evidence

ORD record
ord-c77d63ecb57d46b79b5b9d297ff5355c
Source dataset
uspto-grants-1987_04
Patent number
US04661438

Reaction notes

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