2-Propen-1-yl 1,1,1-trifluoromethanesulfonate → 5-Methoxy-2-methyl-3-(2-propen-1-yl)benzotellurazolium Trifluoromethanesulfonate

HRID 543086Notes

Reaction equation

HRID 543086 reaction equation
[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]2[Te:10][C:9]([CH3:11])=[N:8][C:7]=2[CH:12]=1.[F:13][C:14]([F:23])([F:22])[S:15]([O:18][CH2:19][CH:20]=[CH2:21])(=[O:17])=[O:16]>ClCCl>[F:13][C:14]([F:23])([F:22])[S:15]([O-:18])(=[O:17])=[O:16].[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]2[Te:10][C:9]([CH3:11])=[N+:8]([CH2:21][CH:20]=[CH2:19])[C:7]=2[CH:12]=1

Participants

4

Reactant 2

HCID 109322232-Propen-1-yl 1,1,1-trifluoromethanesulfonateHCID 13931210HCID 13931210, compound

Product 1

HCID 144534235-Methoxy-2-methyl-3-(2-propen-1-yl)benzotellurazolium Trifluoromethanesulfonate

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

5-Methoxy-2-methylbenzotellurazole (Example 20) (0.91 g, 0.033 mole), dissolved in dichloromethane (25 ml), was added at room temperature under a nitrogen atmosphere to the solution of 2-propen-1-yl trifluoromethanesulfonate (0.004 mole) from a dropping funnel. The mixture was stirred at room temperature for another 21 hours after the addition was complete, maintaining the nitrogen atmosphere. The solid was isolated by filtration, washed with diethyl ether, and dried at room temperature under vacuum. Yield 0.90 g.

Workup

  1. additionafter the addition
  2. temperaturemaintaining the nitrogen atmosphere
  3. customThe solid was isolated by filtration
  4. washwashed with diethyl ether
  5. customdried at room temperature under vacuum

Sources & evidence

ORD record
ord-c2651bd118c9444c99e6b13934934f19
Source dataset
uspto-grants-1987_04
Patent number
US04661438

Reaction notes

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