2',4'-Dihydroxyacetophenone → HCID 13881975, compound

HRID 543220Notes

Reaction equation

HRID 543220 reaction equation
Br[CH:2]([CH3:12])[CH2:3][CH2:4][CH2:5][CH2:6][C:7]([O:9]CC)=[O:8].[CH3:13][C:14]([C:16]1[CH:17]=[CH:18][C:19]([OH:23])=[CH:20][C:21]=1[OH:22])=[O:15]>>[C:14]([C:16]1[CH:17]=[CH:18][C:19]([O:23][CH:2]([CH3:12])[CH2:3][CH2:4][CH2:5][CH2:6][C:7]([OH:9])=[O:8])=[CH:20][C:21]=1[OH:22])(=[O:15])[CH3:13]

Participants

3

Reactant 2

HCID 69902',4'-DihydroxyacetophenoneHCID 12939997Heptanoic acid, 6-bromo-, ethyl ester

Product 1

HCID 13881975HCID 13881975, compound

Procedure

Following the procedure of Example 40, 4.74 g. of ethyl 6-bromoheptanoate and 3.04 g. of 2,4-dihydroxyacetophenone were reacted in the usual manner and the resulting product hydrolyzed to give the title product, m.p. about 116°-118° C.

Sources & evidence

ORD record
ord-67193bb0aacd4a14b2fd689deac91c59
Source dataset
uspto-grants-1987_04
Patent number
US04661505

Reaction notes

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