HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Iodide → Methyl 6-(4-acetyl-3-hydroxyphenoxy)-2,2-dimethylhexanoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Iodide | HCID 4875 | — |
| Reactant | 2',4'-Dihydroxyacetophenone | HCID 6990 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | Methyl 6-bromo-2,2-dimethylhexanoate | HCID 15666632 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | Methyl 6-(4-acetyl-3-hydroxyphenoxy)-2,2-dimethylhexanoate | HCID 20205844 | — |
Reaction Steps
Following the procedure of Example 44, 2.5 g. of methyl 6-bromo-2,2-dimethylhexanoate, 1.46 g. of potassium carbonate, a catalytic amount of potassium iodide, and 1.67 g. of 2,4-dihydroxyacetophenone were reacted in 125 ml. of acetone giving 2.3 g. of the title product as an oil. M+ =308; NMR.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04661505 |
| Source dataset | uspto-grants-1987_04 |
| ORD ID | ord-0760d784a7294bdbb00aa767b0b6fbf3 |
| Source note | uspto-grants-1987_04 |