1-[4-(4-Methoxyphenyl)-4-methylpentyl]-3-phenoxybenzene → 1-Fluoro-4-[4-(4-methoxyphenyl)-4-methylpentyl]-2-phenoxybenzene

HRID 543269Notes

Reaction equation

HRID 543269 reaction equation
O(C1C=C(CCCC(C2C=CC(OC)=CC=2)(C)C)C=CC=1)C1C=CC=CC=1.[O:28]([C:35]1[CH:36]=[C:37]([CH2:42][CH:43]=[CH:44][C:45]([C:48]2[CH:53]=[CH:52][C:51]([O:54][CH3:55])=[CH:50][CH:49]=2)([CH3:47])[CH3:46])[CH:38]=[CH:39][C:40]=1[F:41])[C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1.O(C1C=C(C=CCC(C2C=CC(OC)=CC=2)(C)C)C=CC=1F)C1C=CC=CC=1>>[O:28]([C:35]1[CH:36]=[C:37]([CH2:42][CH2:43][CH2:44][C:45]([C:48]2[CH:53]=[CH:52][C:51]([O:54][CH3:55])=[CH:50][CH:49]=2)([CH3:46])[CH3:47])[CH:38]=[CH:39][C:40]=1[F:41])[C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1

Participants

4

Reactant 3

HCID 135322971-[4-(4-Methoxyphenyl)-4-methylpentyl]-3-phenoxybenzeneHCID 54304426HCID 54304426, compoundHCID 54480050HCID 54480050, compound

Product 1

HCID 135564701-Fluoro-4-[4-(4-methoxyphenyl)-4-methylpentyl]-2-phenoxybenzene

Procedure

In the same manner as described in (2) of Synthesis Example 1, the mixture of 1-(3-phenoxy-4-fluorophenyl)-4-(4-methoxyphenyl)-4-methyl-2-pentene and 1-(3-phenoxy-4-fluorophenyl)-4-(4-methoxyphenyl)-4-methyl-1-pentene obtained according to the above (1) was treated to give quantitatively 1-(3-phenoxy-4-fluorophenyl)-4-(4-methoxyphenyl)-4-methylpentane.

Workup

  1. customobtained
  2. additionwas treated

Sources & evidence

ORD record
ord-a35e893363654df9975143d2dfa74b9f
Source dataset
uspto-grants-1987_04
Patent number
US04661501

Reaction notes

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