HuagongsheHuagongshe Chemistry Print Report · For research reference only
Isobutyltriphenylphosphonium bromide → Ethyl 3-methyl-4-[2-methoxy-4-(3-methyl-1-butenyl)phenoxy]2-butenoate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Isobutyltriphenylphosphonium bromide | HCID 2724571 | — |
| Reactant | Ethyl 3-methyl-4-(4-formyl-2-methoxyphenoxy)-2-butenoate | HCID 54099897 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Product | Ethyl 3-methyl-4-[2-methoxy-4-(3-methyl-1-butenyl)phenoxy]2-butenoate | HCID 53772243 | — |
Reaction Steps
Following the above procedures, isobutyltriphenylphosphonium bromide (9.60 g, 24.0 mmol), n-butyllithium (9.0 mmol) and ethyl 3-methyl-4-(4-formyl-2-methoxyphenoxy)-2butenoate (1.67 g, 6.0 mmol) are reacted together to give ethyl 3-methyl-4-[2-methoxy-4-(3-methyl-1-butenyl)phenoxy]2-butenoate, MS m/e 318 (M+).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04661617 |
| Source dataset | uspto-grants-1987_04 |
| ORD ID | ord-e7f0ce9a93cb4cedaaf2b8f2e60bddfb |
| Source note | uspto-grants-1987_04 |