HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → 2-Propenoic acid, 3-(4-chlorophenyl)-, ethyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Methanol | HCID 887 | — |
| Reactant | Styrene | HCID 7501 | — |
| Reactant | 4-Chlorostyrene | HCID 14085 | — |
| Catalyst | Palladium Chloride | HCID 24290 | — |
| Product | 2-Propenoic acid, 3-(4-chlorophenyl)-, ethyl ester | HCID 201471 | 60.2% |
Reaction Steps
The procedures of Example 27 were exactly followed except that p-chlorostyrene and ethanol were used respectively instead of styrene and methanol and the amount of palladium chloride was changed to 0.1 millimole. Ethyl 4-chlorocinnamate was obtained with a yield of 60.2%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04661620 |
| Source dataset | uspto-grants-1987_04 |
| ORD ID | ord-6f402cd1951d44a9b4643cffbe16cf59 |
| Source note | uspto-grants-1987_04 |