HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl iodide → 4-tert-Butyl-2-(methanesulfonyl)-1-methoxybenzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl iodide | HCID 6328 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | HCID 13210234 | HCID 13210234 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | 4-tert-Butyl-2-(methanesulfonyl)-1-methoxybenzene | HCID 12721565 | — |
Reaction Steps
17.4 g (0.076 mol) of 3-(1,1-dimethylethyl)-6-methoxybenzenesulfinic acid are suspended in 120 ml of acetone, and 13.3 ml (0.095 mol) of triethylamine and 8.5 ml (0.12 mol) of iodomethane are added. The mixture is stirred at room temperature for 2 hours and then poured onto ice-water. The precipitate which separates out is filtered off with suction and recrystallized from N-butanol.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04661636 |
| Source dataset | uspto-grants-1987_04 |
| ORD ID | ord-7fa0fd4a64fa42e292b09e0f1c4eef59 |
| Source note | uspto-grants-1987_04 |