HuagongsheHuagongshe Chemistry Print Report · For research reference only
Dimethylformamide → HCID 13851149, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Dimethylformamide | HCID 6228 | — |
| Reactant | Ethyl bromoacetate | HCID 7748 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | HCID 15617000 | HCID 15617000 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 13851149 | HCID 13851149 | 67.9% |
Reaction Steps
A mixture of 1.2 g of 4-chloro-3-hydroxy-9-oxo-9H-xanthene, 1.7 g of potassium carbonate, 2.1 g of ethyl bromoacetate and 30 ml of DMF was stirred at 60°-70° C. for 3 hours. After cooling the mixture, water was added and the resulting crystal was recovered by filtration, washed with water and dried. Recrystallization from ethanol gave 1.1 g of ethyl 4-chloro-9-oxo-9H-xanthene-3-yloxyacetate. m.p. 183°-185° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04661607 |
| Source dataset | uspto-grants-1987_04 |
| ORD ID | ord-0747d5ee95e84eee9d9ad7b3c0514dcc |
| Source note | uspto-grants-1987_04 |