HCID 20259244, compound → HCID 86739268, compound

HRID 544692Notes

Reaction equation

HRID 544692 reaction equation
C1C2C3C=CC=CC=3CCCC=2C(CO)=CC=1.ClC(C(CF)(CF)CF)=C[C@@H]1[C@H](C(Cl)=O)C1(C)C.[Cl:36][C:37]([C:63]([CH2:68][F:69])([CH2:66][F:67])[CH2:64][F:65])=[CH:38][C@@H:39]1[C@H:41]([C:42]([O:44][CH2:45][C:46]2[C:51]3[CH2:52][CH2:53][CH2:54][C:55]4[CH:60]=[CH:59][CH:58]=[CH:57][C:56]=4[C:50]=3[CH:49]=[CH:48][CH:47]=2)=[O:43])[C:40]1([CH3:62])[CH3:61]>>[Cl:36][C:37]([C:63]([CH2:68][F:69])([CH2:64][F:65])[CH2:66][F:67])=[CH:38][CH:39]1[CH:41]([C:42]([O:44][CH2:45][C:46]2[C:51]3[CH2:52][CH2:53][CH2:54][C:55]4[CH:60]=[CH:59][CH:58]=[CH:57][C:56]=4[C:50]=3[CH:49]=[CH:48][CH:47]=2)=[O:43])[C:40]1([CH3:61])[CH3:62]

Participants

4

Reactant 3

HCID 20259244HCID 20259244, compoundHCID 86739269cis-3-(2-Chloro-3,3,3-trifluoromethyl-1-propenyl)-2,2-dimethylcyclopropanecarbonyl chlorideHCID 86739270HCID 86739270, compound

Product 1

HCID 86739268HCID 86739268, compound

Procedure

In the manner of Example I, but substituting 6,7-dihydro-5H-dibenzo[a,c]cycloheptene-4-methanol and cis-3-(2-chloro-3,3,3-trifluoromethyl-1-propenyl)-2,2-dimethylcyclopropanecarbonyl chloride, (6,7-dihydro-5H-dibenzo[a,c]cyclohepten-4-yl)methyl cis-3-(2-chloro-3,3,3-trifluoromethyl-1-propenyl)-2,2-dimethylcyclopropanecarboxylate was prepared.

Workup

  1. customwas prepared

Sources & evidence

ORD record
ord-34b45b672e8f4ba4adfc686265ec3c03
Source dataset
uspto-grants-1984_05
Patent number
US04451484

Reaction notes

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