Iodine → HCID 86739437, compound

HRID 544699Notes

Reaction equation

HRID 544699 reaction equation
[I-].[K+].II.[CH3:5][CH2:6][C:7]([NH:9][C:10]1[CH:11]=[C:12]([N:16]2[C:20]([SH:21])=[N:19][N:18]=[N:17]2)[CH:13]=[CH:14][CH:15]=1)=[S:8]>O.C(O)C>[CH3:5][CH2:6][C:7]([NH:9][C:10]1[CH:11]=[C:12]([N:16]2[C:20]([S:21][S:21][C:20]3[N:16]([C:12]4[CH:13]=[CH:14][CH:15]=[C:10]([NH:9][C:7](=[S:8])[CH2:6][CH3:5])[CH:11]=4)[N:17]=[N:18][N:19]=3)=[N:19][N:18]=[N:17]2)[CH:13]=[CH:14][CH:15]=1)=[S:8]

Participants

6

Reactant 3

HCID 807IodineHCID 4875Potassium IodideHCID 178460995HCID 178460995, compound

Product 1

HCID 86739437HCID 86739437, compound

Reagents, catalysts & solvents 2

HCID 702EthanolSolventHCID 962WaterSolvent

Procedure

A solution of 3.0 g of potassium iodide and 3.2 g of iodine in 50 ml of water and 25 ml of ethanol was added dropwise with stirring and at room temperature to 7 g of 1-[m-(methylthioacetylamino)-phenyl]-5-mercaptotetrazole. The precipitate was purified by recrystallization from methanol.

Workup

  1. customThe precipitate was purified by recrystallization from methanol

Sources & evidence

ORD record
ord-71d8dd23f5b44319ac4f93e54b9f9c07
Source dataset
uspto-grants-1984_05
Patent number
US04451555

Reaction notes

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