Nitric Acid → HCID 67194514, compound

HRID 544793Notes

Reaction equation

HRID 544793 reaction equation
[C:1]([O:9][C:10]1[CH:19]=[CH:18][C:17]2[C:12](=[CH:13][CH:14]=[C:15]([OH:20])[CH:16]=2)[CH:11]=1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[N+:21]([O-])([OH:23])=[O:22].O>C(O)(=O)C>[C:1]([O:9][C:10]1[CH:19]=[CH:18][C:17]2[C:12](=[CH:13][CH:14]=[C:15]([OH:20])[C:16]=2[N+:21]([O-:23])=[O:22])[CH:11]=1)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 944Nitric AcidHCID 962WaterHCID 15279123HCID 15279123, compound

Product 1

HCID 67194514HCID 67194514, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

The thus obtained 6-hydroxy-2-naphthyl benzoate was dispersed in acetic acid, nitric acid was added dropwise to the dispersion while keeping it at 15° C., and water was further added thereto, followed by stirring. The thus obtained deposit was recrystallized from ethanol/acetic acid to obtain 6-hydroxy-5-nitro-2-naphthyl benzoate.

Workup

  1. customat 15° C.
  2. customThe thus obtained deposit was recrystallized from ethanol/acetic acid

Sources & evidence

ORD record
ord-55cefff41d0346b1bd2437b3200c3d54
Source dataset
uspto-grants-2011_05
Patent number
US07935395B2

Reaction notes

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