Geranylacetone → 6,10-Dimethylundecan-2-one

HRID 546383Notes

Reaction equation

HRID 546383 reaction equation
[CH2:1]([CH2:11][C:12](=[O:14])[CH3:13])/[CH:2]=[C:3](/[CH2:5][CH2:6][CH:7]=[C:8]([CH3:10])[CH3:9])\[CH3:4]>[Pd]>[CH3:10][CH:8]([CH2:7][CH2:6][CH2:5][CH:3]([CH2:2][CH2:1][CH2:11][C:12]([CH3:13])=[O:14])[CH3:4])[CH3:9]

Participants

3

Reactant 1

HCID 1549778Geranylacetone

Product 1

HCID 954956,10-Dimethylundecan-2-one

Reagents, catalysts & solvents 1

HCID 23938PalladiumCatalyst

Procedure

In analogy to the procedure and apparatus described in Example 1 but employing a 0.5% (wt./wt.) Pd on Al2O3 catalyst (DEGUSSA, E257H/D) geranylacetone was hydrogenated to produce hexahydropseudoionone. The process parameters were as stated below:

Sources & evidence

ORD record
ord-54e938921b9e44868f363ad9b6fbf010
Source dataset
uspto-grants-2011_05
Patent number
US07935849B2

Reaction notes

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