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HRID54821

反应详情

EQUATION

反应方程式

HRID 54821 的结构方程式

REACTANTS

反应物

2
结构：CC(=O)O
HCID176

Acetic Acid

C2H4O2

结构：CC(Cl)OC(=O)Oc1ccc([N+](=O)[O-])cc1
HCID10538354

1-Chloroethyl 4-nitrophenyl carbonate

C9H8ClNO5

PRODUCTS

生成物

1
结构：CC(=O)OC(C)OC(=O)Oc1ccc([N+](=O)[O-])cc1
HCID11780560

1-acetoxyethyl p-nitrophenyl carbonate

C11H11NO7

PROCEDURE

实验过程

To a solution of 10.0 g of product from Example 317 in 250 ml of acetic acid is added 15.0 g mercuric acetate. The mixture is stirred at room temperature for 22 hours, concentrated in vacuo, and purified by chromatography (Silica gel: methylene chloride -5% methyl alcohol/methylene chloride) to give 7.5 g of the desired product.

WORKUP

后处理

  1. concentrationconcentrated in vacuo
  2. custompurified by chromatography (Silica gel: methylene chloride -5% methyl alcohol/methylene chloride)