化工社化工社 化学情報印刷レポート · 研究参考用
Triethylamine → 3-[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]thio]-N,N-dicyclohexylpropanamide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Triethylamine | HCID 8471 | — |
| 反応物 | 2,6-Di-tert-butyl-4-mercaptophenol | HCID 70370 | — |
| 反応物 | 2-Propenamide, N,N-dicyclohexyl- | HCID 10105498 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | 3-[[3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl]thio]-N,N-dicyclohexylpropanamide | HCID 9826140 | — |
反応手順
The title compound of Example 3 (1.9 g, 0.008 mole), 2,6-bis(1,1-dimethylethyl)-4-mercaptophenol(2 g, 0.008 mole) and triethylamine (0.5 ml) were stirred in methanol (25 ml) for about 12 hours. The solvent was removed in vacuo on a rotary evaporator, the crude material purified by chromatography on silica and recrystallized from hexane, m.p. ca. 168.5°-172° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05244899 |
| 出典データセット | uspto-grants-1993_09 |
| ORD ID | ord-83a7fad34b684fd8a233fc5ded25c4c5 |
| 出典メモ | uspto-grants-1993_09 |