HCID 53911528, compound → 3-Bromo-6-methoxyphenanthrene

HRID 549494Notes

Reaction equation

HRID 549494 reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]=[CH:9][C:10]2[CH:15]=[CH:14][C:13]([O:16][CH3:17])=[CH:12][CH:11]=2)=[CH:4][CH:3]=1.BrC1C=CC(C=CC2C=CC(Cl)=CC=2)=CC=1>>[Br:1][C:2]1[CH:3]=[CH:4][C:5]2[CH:8]=[CH:9][C:10]3[C:11]([C:6]=2[CH:7]=1)=[CH:12][C:13]([O:16][CH3:17])=[CH:14][CH:15]=3

Participants

3

Reactant 2

HCID 53911528HCID 53911528, compoundHCID 541582251-Bromo-4-[2-(4-methoxyphenyl)ethenyl]benzene

Product 1

HCID 866148773-Bromo-6-methoxyphenanthrene

Procedure

This phenanthrene was prepared as described in Step 2 of Example 36, substituting 1-bromo-4-[2-(4-methoxyphenyl)vinyl]benzene from Step 1 above for 1-bromo-4-[2-(4-chlorophenyl)vinyl]benzene and performing the irradiation for 4 days.

Workup

  1. customthe irradiation for 4 days

Sources & evidence

ORD record
ord-bd83a9275f2e40258eb9bf809e9f8326
Source dataset
uspto-grants-2011_05
Patent number
US07943649B2

Reaction notes

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