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HRID549984

反应详情

EQUATION

反应方程式

HRID 549984 的结构方程式

REACTANTS

反应物

2
结构：CCC[CH2][Sn]([CH2]CCC)([CH2]CCC)[c]1ncccn1
HCID2763251

2-(tributylstannyl)pyrimidine

C16H30N2Sn

结构：COc1c(Cc2ccc(Br)s2)cc([C@@H]2O[C@H](COC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]2OC(C)=O)c2ccccc12
HCID66607611

未命名化合物

PRODUCTS

生成物

1
结构：COc1c(Cc2ccc(-c3ncccn3)s2)cc([C@@H]2O[C@H](CO)[C@@H](O)[C@H](O)[C@H]2O)c2ccccc12
HCID67157890

未命名化合物

PROCEDURE

实验过程

1-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-3-(5-bromo-2-thienylmethyl)-4-methoxylnaphthalene obtained in Example 265-(3) and 2-tributylstannylpyrimidine were treated in a manner similar to Example 128-(5) and (6) to give 1-(β-D-glucopyranosyl)-3-(5-(2-pyrimidinyl)-2-thienyl-methyl)-4-methoxylnaphthalene. APCI-Mass m/Z 495 (M+H).