Acrylic Acid → Aluminum triacrylate

HRID 550051Notes

Reaction equation

HRID 550051 reaction equation
C([O-])(C)C.C([O-])(C)C.C([O-])(C)C.[Al+3:13].[C:14]([OH:18])(=[O:17])[CH:15]=[CH2:16]>>[C:14]([O-:18])(=[O:17])[CH:15]=[CH2:16].[C:14]([O-:18])(=[O:17])[CH:15]=[CH2:16].[C:14]([O-:18])(=[O:17])[CH:15]=[CH2:16].[Al+3:13]

Participants

3

Reactant 2

HCID 6581Acrylic AcidHCID 11143Aluminum isopropoxide

Product 1

HCID 167353Aluminum triacrylate

Conditions

Temperature
32 °C

Procedure

Into the flask described hereinabove there were placed 204.2 grams of aluminium tri-isopropanolate to which 216 grams of acrylic acid were added during 8 minutes at room temperature (25° C.). The procedure was as set forth hereinabove. Owing to the reaction heat, the temperature increased to 32° C. The resultant product was a white, solid substance. The rotary evaporator heating then was switched on and gradually heated to 70° C. At the same time the vacuum was gradually adjusted to 24 mbar. The isopropanol was thereby expelled yielding a white powder.

Workup

  1. additionwere added during 8 minutes at room temperature (25° C.)
  2. temperatureOwing to the reaction heat
  3. customThe rotary evaporator
  4. temperatureheating
  5. temperaturegradually heated to 70° C
  6. customThe isopropanol was thereby expelled yielding a white powder

Sources & evidence

ORD record
ord-3d8f303b041a4fbba442edeaeb88f3c3
Source dataset
uspto-grants-2011_05
Patent number
US07943798B2

Reaction notes

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