Acrylic Acid → Zirconium(4+) tetraprop-2-enoate

HRID 550053Notes

Reaction equation

HRID 550053 reaction equation
[Zr:1].[C:2]([OH:6])(=[O:5])[CH:3]=[CH2:4]>>[C:2]([O-:6])(=[O:5])[CH:3]=[CH2:4].[C:2]([O-:6])(=[O:5])[CH:3]=[CH2:4].[C:2]([O-:6])(=[O:5])[CH:3]=[CH2:4].[C:2]([O-:6])(=[O:5])[CH:3]=[CH2:4].[Zr+4:1]

Participants

3

Reactant 2

HCID 6581Acrylic AcidHCID 23995Zirconium

Product 1

HCID 14497031Zirconium(4+) tetraprop-2-enoate

Conditions

Temperature
35 °C

Procedure

Into the flask described hereinabove there were placed 1,021.3 g of zirconium tetrabutylate to which 767.5 grams of acrylic acid were added during 8 minutes at room temperature (25° C.). The procedure was as set forth hereinabove. Owing to the reaction heat, the temperature increased to 35° C. The resultant product was a white, solid substance. The rotary evaporator heating then was switched on and gradually heated to 90° C. At the same time the vacuum was gradually adjusted to 20 mbar. The butanol was thereby expelled yielding a white powder.

Workup

  1. additionwere added during 8 minutes at room temperature (25° C.)
  2. temperatureOwing to the reaction heat
  3. customThe rotary evaporator
  4. temperatureheating
  5. temperaturegradually heated to 90° C
  6. customThe butanol was thereby expelled yielding a white powder

Sources & evidence

ORD record
ord-8e844675381e44c986e452f9c95d8d96
Source dataset
uspto-grants-2011_05
Patent number
US07943798B2

Reaction notes

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