HuagongsheHuagongshe Chemistry Print Report · For research reference only
Nitric Acid → 5-Chloro-4-nitro-2,1,3-benzoselenadiazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Nitric Acid | HCID 944 | — |
| Reactant | 5-Chloro-2,1,3-benzoselenadiazole | HCID 413575 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Sulfuric Acid | HCID 1118 | — |
| Product | 5-Chloro-4-nitro-2,1,3-benzoselenadiazole | HCID 4366221 | — |
Reaction Conditions
| Temperature | 0 °C |
|---|
Reaction Steps
A solution of 5-chloro-2,1,3-benzoselenadiazole from Step A (800 mg, 1.80 mmol) in conc. H2SO4 (12 mL) was cooled to 0° C. and 90% HNO3 (0.8 mL) was added. After 30 min the reaction was cooled to 0° C. and diluted with H2O (10 mL). The solid was filtered off and washed with cold 1420 to yield the title compound. MS: m/z=263 (M+1).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07947677B2 |
| Source dataset | uspto-grants-2011_05 |
| ORD ID | ord-82b6c0aafb1a4ebd8d99f96968380237 |
| Source note | uspto-grants-2011_05 |