HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tetrabutylammonium Fluoride → N-benzenesulfonyl-4-ethinylbenzoic acid amide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tetrabutylammonium Fluoride | HCID 2724141 | — |
| Reactant | N-benzenesulfonyl-4-(2-trimethylsilylethinyl)-benzoic acid amide | HCID 53860484 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | N-benzenesulfonyl-4-ethinylbenzoic acid amide | HCID 54259246 | 121.3% |
Reaction Steps
Under the conditions of example 21 C, a solution of 3.1 g of N-benzenesulfonyl-4-(2-trimethylsilylethinyl)-benzoic acid amide in 200 ml of tetrahydrofuran is reacted with 9.5 ml of a 1-molar solution of tetrabutylammonium fluoride in tetrahydrofuran and worked up. 3 g of N-benzenesulfonyl-4-ethinylbenzoic acid amide is obtained as crude product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05624943 |
| Source dataset | uspto-grants-1997_04 |
| ORD ID | ord-3b343080f14e43bba26e9ab2084b6e19 |
| Source note | uspto-grants-1997_04 |