Carbon Tetrachloride → HCID 57834544, compound

HRID 555206Notes

Reaction equation

HRID 555206 reaction equation
[CH3:1][O:2][Si:3]([O:12][CH3:13])([O:10][CH3:11])[CH2:4][SiH:5]([O:8][CH3:9])[O:6][CH3:7].C(Cl)(Cl)(Cl)[Cl:15]>[Pd](Cl)Cl>[Cl:15][Si:5]([O:8][CH3:9])([O:6][CH3:7])[CH2:4][Si:3]([O:12][CH3:13])([O:10][CH3:11])[O:2][CH3:1]

Participants

4

Reactant 2

HCID 5943Carbon TetrachlorideHCID 123335979HCID 123335979, compound

Product 1

HCID 57834544HCID 57834544, compound

Reagents, catalysts & solvents 1

HCID 24290Palladium ChlorideCatalyst

Procedure

A solution of 7.27 mmol (1.29 g) of palladium (II) dichloride [PdCl2 (II)] in 30 ml of carbon tetrachloride is placed in a flask, and then 0.106 moles (24 g) of 1,1,1,3,3-pentamethoxy-1,3-disilapropane (98%, Korea Institute of Science and Technology (KIST)) is slowly added thereto at 0° C. The reaction is allowed to proceed at this temperature for 4 hours. The reaction mixture is filtered through celite to obtain 3-chloro-1,1,1,3,3-pentamethoxy-1,3-disilapropane.

Workup

  1. customat 0° C
  2. filtrationThe reaction mixture is filtered through celite

Sources & evidence

ORD record
ord-32303c895fb1451c9ae132c23c41dbf1
Source dataset
uspto-grants-2011_11
Patent number
US08053173B2

Reaction notes

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