Triethylamine → HCID 131729264, compound

Participants

Reaction Conditions

Reaction Steps

A solution of 4-(diallylethoxysilyl)aniline (153 mg, 0.62 mmol) and distilled dichloromethane (dist. CH2Cl2: 5 mL) was added with dist. Et3N (86 μL, 0.62 mmol), and then acryloyl chloride (50 μL, 0.62 mmol) was added dropwise slowly at 0° C. The mixture thus obtained was stirred under a nitrogen atmosphere at 0° C. for 8 hours. After that, the solvent in the mixture was distilled without being heated to obtain a residue. Subsequently, the residue thus obtained was separated and purified by PTLC (hexane/EtOAc=2/1) to obtain 1-acryloylamino-4-(diallylethoxysilyl)benzene (110 mg, 59% yield).

Provenance & Evidence