HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 556391Generated: October 31, 2026
Tributylstannane → (E)-3-(tributylstannyl)prop-2-en-1-ol
https://huagongshe.com/reaction/556391
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Tributylstannane | HCID 5948 | — |
| Reactant | Propargyl alcohol | HCID 7859 | — |
| Reactant | 1,1'-Azobis(cyclohexanecarbonitrile) | HCID 74978 | — |
| Product | (E)-3-(tributylstannyl)prop-2-en-1-ol | HCID 10043273 | — |
Reaction Steps
To neat propargyl alcohol (1.77 mL) were added tributyltin hydride (10.3 mL) followed by 1,1′-azobis(cyclohexanecarbonitrile) (378 mg). The mixture was heated for 2.5 h at 80° C., cooled to RT and directly purified by CC (EA/Hept 5/95) to afford the desired compound (5.4 g).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US08058263B2 |
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| Source dataset | uspto-grants-2011_11 |
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| ORD ID | ord-cc5cd37012cd41fdbee014590d90853e |
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| Source note | uspto-grants-2011_11 |
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