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HRID557333

反应详情

EQUATION

反应方程式

HRID 557333 的结构方程式

REACTANTS

反应物

2
结构：O=[N+]([O-])[O-].[K+]
HCID24434

Potassium nitrate

KNO3

结构：CC1(C)NS(=O)(=O)c2ccccc21
HCID4447355

2,3-Dihydro-3,3-dimethyl-1,2-benzisothiazole 1,1-dioxide

C9H11NO2S

PRODUCTS

生成物

1
结构：CC1(C)NS(=O)(=O)c2cc([N+](=O)[O-])ccc21
HCID22249372

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：O=S(=O)(O)O
溶剂HCID1118

Sulfuric acid

H2O4S

CONDITIONS

反应条件

温度
0 °C

PROCEDURE

实验过程

3,3-Dimethyl-2,3-dihydro-benzo[d]isothiazole 1,1-dioxide was added to KNO3 in H2SO4 cooled to 0° C. and stirred for 15 min. The reaction was warmed to RT and stirred overnight. The mix was poured into ice and extracted with EtOAc (3×), washed with H2O and brine, dried and evaporated to give the product which was used without further purification.

WORKUP

后处理

  1. temperatureThe reaction was warmed to RT
  2. stirringstirred overnight
  3. additionThe mix was poured into ice
  4. extractionextracted with EtOAc (3×)
  5. washwashed with H2O and brine
  6. customdried
  7. customevaporated
  8. customto give the product which
  9. customwas used without further purification