Sodium hydride → HCID 178425994, compound

Participants

Reaction Steps

Solution of 2-isopropyl-6-phenylphenol (700 mg, 3.28 mmol) and sodium hydride (236 mg, 9.84 mmol) in toluene (10 mL) was subjected to reaction under reflux for 4 hours. Then, the mixture was cooled to ambient temperature, and solution of (trichloro)(pentamethylcyclopentadienyl)titanium (IV) (930 mg, 3.21 mmol) dissolved in toluene (5 mL) was slowly added dropwise thereto. The resultant mixture was reacted under reflux for 24 hours. When the reaction was completed, volatile substances were removed therefrom, and the residue was washed with purified hexane. Recrystallization from toluene/hexane mixed solvent at −35° C., followed by filtration and drying under reduced pressure gave red solid (1.0 g).

Provenance & Evidence