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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 564296Generated: October 29, 2026

tert-Butanol → 2,4,4-Trimethyl-1-pentene

https://huagongshe.com/reaction/564296

Reaction equation

Participants

RoleNameHCIDCharge
Reactanttert-ButanolHCID 6386—
ReactantIsobutyleneHCID 8255—
SolventWaterHCID 962—
Product2,4,4-Trimethyl-1-penteneHCID 7868—
ProductIsobutyleneHCID 8255—

Reaction Steps

This invention is a process for producing diisobutylene. The process comprises first contacting a sulfonic acid resin with a reaction feed comprising isobutylene and tertiary butyl alcohol to produce a product stream comprising diisobutylene, isobutylene, tertiary butyl alcohol, and water. The product stream is distilled to produce a first overhead stream comprising water and isobutylene and a first bottoms stream comprising diisobutylene and tertiary butyl alcohol. Water is separated from the first overhead stream, and the resulting isobutylene-enriched stream is recycled back to the reaction step. The first bottoms stream is distilled to produce a bottoms product stream comprising diisobutylene and a second overhead stream comprising tertiary butyl alcohol and diisobutylene.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS08067655B2
Source datasetuspto-grants-2011_11
ORD IDord-f28570b5576145e6b8eac51de6eec624
Source noteuspto-grants-2011_11