HCID 22112806, compound → HCID 22112815, compound

HRID 564718Notes

Reaction equation

HRID 564718 reaction equation
[O:1]1[CH2:6][CH:5]=[C:4]([C:7]2[O:17][C:10]3=[C:11]([O:15][CH3:16])[N:12]=[CH:13][CH:14]=[C:9]3[CH:8]=2)[CH2:3][CH2:2]1>C(O)C.[Ni]>[CH3:16][O:15][C:11]1[N:12]=[CH:13][CH:14]=[C:9]2[CH:8]=[C:7]([CH:4]3[CH2:5][CH2:6][O:1][CH2:2][CH2:3]3)[O:17][C:10]=12

Participants

4

Reactant 1

HCID 22112806HCID 22112806, compound

Product 1

HCID 22112815HCID 22112815, compoundYield 99.1%

Reagents, catalysts & solvents 2

HCID 935NickelCatalystHCID 702EthanolSolvent

Procedure

A solution of the alkene (1.0 g) in ethanol (50 ml) was treated with Raney Nickel and hydrogenated at atmospheric pressure for 4 hours. The mixture was filtered through Celite and the solvent was removed in vacuo to give the title compound (1.0 g) as a creamy oil.

Workup

  1. filtrationThe mixture was filtered through Celite
  2. customthe solvent was removed in vacuo

Sources & evidence

ORD record
ord-6842d8a3581f4e8390a5e69fb5ad4ad8
Source dataset
uspto-grants-2001_01
Patent number
US06169090A

Reaction notes

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