Water → HCID 70217200, compound

HRID 565155Notes

Reaction equation

HRID 565155 reaction equation
[CH:1]([CH:4]1[CH2:9][CH2:8][CH:7]([C:10]([O:12]CC)=[O:11])[CH2:6][CH2:5]1)=[CH:2][CH3:3].[OH-].[Na+].O>C(O)C>[CH:1]([CH:4]1[CH2:9][CH2:8][CH:7]([C:10]([OH:12])=[O:11])[CH2:6][CH2:5]1)=[CH:2][CH3:3]

Participants

5

Reactant 3

HCID 962WaterHCID 14798Sodium HydroxideHCID 70219337Ethyl 4-propenylcyclohexanecarboxylate

Product 1

HCID 70217200HCID 70217200, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

170 g of ethyl 4-propenylcyclohexanecarboxylate from Example 2, 38 g of sodium hydroxide, 215 ml of water and 1075 ml of ethanol were combined and stirred overnight at RT. Conventional work-up gave 4-propenylcyclohexanecarboxylic acid as an E/Z isomer mixture.

Sources & evidence

ORD record
ord-288e60780d894531bce8602311cc9fe6
Source dataset
uspto-grants-2001_01
Patent number
US06171664B2

Reaction notes

Loading…