HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → 5-[(Tricyclo[3.3.1.1~3,7~]decan-1-yl)methoxy]pentanal
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | 1-{[(5,5-Diethoxypentyl)oxy]methyl}tricyclo[3.3.1.1~3,7~]decane | HCID 21264488 | — |
| Solvent | Acetone | HCID 180 | — |
| Product | 5-[(Tricyclo[3.3.1.1~3,7~]decan-1-yl)methoxy]pentanal | HCID 16106703 | — |
Reaction Steps
A mixture of the appropriate acetal 5, 6, (0.2 mmol) in 3 ml acetone and 1 ml 5% HCl was stirred at rt for 1h. Evaporation of the acetone, extraction of the residue with ether (3×7ml), drying on Na2SO4 and evaporation yielded the aldehyde (quant.) used for the next step without further purification.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06177447B1 |
| Source dataset | uspto-grants-2001_01 |
| ORD ID | ord-3f8a438ff98143ab884f119e64fa971e |
| Source note | uspto-grants-2001_01 |