HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl orthoformate → N-diethoxymethyltriazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl orthoformate | HCID 31214 | — |
| Reactant | HCID 178418936 | HCID 178418936 | — |
| Catalyst | p-Toluenesulfonic acid monohydrate | HCID 521998 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | N-diethoxymethyltriazole | HCID 22280793 | 56.8% |
Reaction Steps
After the addition of 2.5 g of p-toluenesulphonic acid hydrate, 34.5 g (0.5 mol) of triazole in 222 g (1.5 mol) of triethyl orthoforrnate are heated until the internal temperature reaches 150° C., while ethanol is distilled off. 2 g of sodium carbonate are added and the mixture is distilled using high vacuum. 48.6 g (56.8% of theory) of N-diethoxymethyltriazole are obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06177459B1 |
| Source dataset | uspto-grants-2001_01 |
| ORD ID | ord-fe972614f61442adbbc6e82f0b3b88b3 |
| Source note | uspto-grants-2001_01 |