Dicyclopentadiene → 1,2,3,4,4a,5,8,8a-Octahydro-1,4:5,8-dimethanonaphth-2-yl acetate

Participants

Reaction Steps

The reaction was carried out in the same manner as in the Synthesis Example 1(1), except for using vinyl acetate, dicyclopentadiene, and 5-acetoxycarbonylbicyclo[2.2.1]hept-2-ene at a molar ratio of 3:1(as cyclopentadiene):1 as reaction raw materials, to obtain 8-acetoxytetracyclo[4.4.0.12,5.17,10]dodec-3-ene of the following formula (13) at an yield of 36%.

Provenance & Evidence