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HRID567930

反应详情

EQUATION

反应方程式

HRID 567930 的结构方程式

REACTANTS

反应物

4
结构：O=S(=O)(O)O
HCID1118

Sulfuric acid

H2O4S

结构：O=[N+]([O-])OCC(CO)(CO[N+](=O)[O-])CO[N+](=O)[O-]
HCID15353

1,3-Propanediol, 2,2-bis[(nitrooxy)methyl]-, 1-nitrate

C5H9N3O10

结构：O=S([O-])O
HCID104748

Sulfurous acid, ion(1-)

HO3S-

结构：[K+].[O]=[Mn](=[O])(=[O])[O-]
HCID516875

Potassium permanganate

KMnO4

PRODUCTS

生成物

1
结构：O=C(O)C(CO[N+](=O)[O-])(CO[N+](=O)[O-])CO[N+](=O)[O-]
HCID9882291

Propanoic acid, 3-(nitrooxy)-2,2-bis[(nitrooxy)methyl]-

C5H7N3O11

收率 72%

AUXILIARIES

试剂、催化剂与溶剂

3
结构：CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC.[Cl-]
催化剂HCID21218

未命名化合物

结构：c1ccccc1
溶剂HCID241

Benzene

C6H6

结构：O
溶剂HCID962

Water

H2O

PROCEDURE

实验过程

0.0074 mol of KMnO4 is added in portions, with vigorous stirring, to a solution of 0.0037 mol of pentaerythrityl trinitrate (PETriN), 5.5 ml of benzene, 9 ml of water and 0.15 ml of Aliquat® 336. When the addition has ended, the temperature is kept at 15° C. for 2 hours. Aqueous hydrogensulfite solution is then added, the mixture is acidified with H2SO4 and the benzene layer is separated off. After removal of the solvent, 3-nitryloxy-2,2-bis(nitryloxymethyl)propionic acid (Tri-PA) is obtained as a solid residue, which is recrystallized several times from methylene chloride. Yield: 72%.

WORKUP

后处理

  1. additionWhen the addition
  2. customthe benzene layer is separated off
  3. customAfter removal of the solvent