Toluene → 4-Hydroxyphenylthio cyclododecadiene

HRID 568299Notes

Reaction equation

HRID 568299 reaction equation
[SH:1][C:2]1[CH:7]=[CH:6][C:5]([OH:8])=[CH:4][CH:3]=1.[CH:9]1[CH2:20][CH2:19]C=CCCC=C[CH2:12][CH2:11][CH:10]=1.[C:21]1(C)[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=1>>[OH:8][C:5]1[CH2:4][CH2:3][CH2:12][CH2:11][CH2:10][CH2:9][CH2:20][CH2:19][C:2]([S:1][C:21]2[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=2)=[CH:7][CH:6]=1

Participants

4

Reactant 3

HCID 1140TolueneHCID 126681,5,9-CyclododecatrieneHCID 2401474-Mercaptophenol

Product 1

HCID 704100744-Hydroxyphenylthio cyclododecadiene

Conditions

Temperature
40 °C

Procedure

To the reactor of Example 1 was added 100.8 grams of 4-mercaptophenol and 100 ml toluene. While maintaining the reaction mixture at 40° C. 32.6 grams of 1,5,9-cyclododecatriene was added over a 20 minute period. The mixture was agitated for 24 hours and then stripped to a pot temperature of 220° C. and 11 mm. Hg. to yield 46 grams of product.

Workup

  1. customstripped to a pot temperature of 220° C. and 11 mm. Hg

Sources & evidence

ORD record
ord-b84dacefed204e408afb7dc970ae2e32
Source dataset
uspto-grants-1988_03
Patent number
USRE032618

Reaction notes

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