Disilane, 1,1-dichloro-1,2,2,2-tetramethyl- → HCID 178448655, compound

Participants

Reaction Steps

A reaction mixture containing 5 gm (0.021 moles) of n-butyl-4-chlorophthalimide and 3.95 gm (0.021 moles) of 1.2 dichlorotetramethyldisilane dissolved in 10 ml of o-xylene was heated to 150° C. in the presence of 5 mole % tetrakis(triphenylphosphine)palladium. After 24 hours reaction time, GC and GC/MS analysis showed a 24% yield of N-butyl-4-chlorodimethylsilyl-phthalimide. The product is readily isolatable by vacuum distillation.

Provenance & Evidence