Sodium Carbonate → Zirconium

HRID 568949Notes

Reaction equation

HRID 568949 reaction equation
[Zr:1].[CH2:2]([CH:4]([CH2:8][CH2:9][CH2:10][CH3:11])[C:5]([O-:7])=[O:6])[CH3:3].[OH-].[Na+:13].C(=O)([O-])[O-].[Na+].[Na+]>O>[CH2:2]([CH:4]([CH2:8][CH2:9][CH2:10][CH3:11])[C:5]([O-:7])=[O:6])[CH3:3].[Na+:13].[Zr:1]

Participants

7

Reactant 4

HCID 10340Sodium CarbonateHCID 14798Sodium HydroxideHCID 23995Zirconium3×HCID 40723562-Ethylhexanoate

Product 2

HCID 23995ZirconiumHCID 23672331Sodium 2-ethylhexanoate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

Solution A was prepared by the addition of 300 g of zirconium acid sulfate to 370 g of water. A second aqueous solution (Solution B) containing an excess amount of base in an amount of 0.101 excess equivalents per equivalent of the zirconium acid sulfate of Solution A was prepared as follows: Sodium 2-ethylhexanoate was prepared in situ by adding 133.0 g of 2-ethylhexanoate acid to 643.4 g of water and a neutralizing amount of 73.9 g of sodium hydroxide (an exact equivalent). Sodium carbonate was added in an amount of 155.4 g to provide a 10.1% excess of basic equivalents per equivalent of zirconium acid sulfate. An amount of 373.7 g of mineral spirits and 15.3 g of butyl cabitol was added to provide organic phase material for product collection before combining the solutions.

Workup

  1. customwas prepared

Sources & evidence

ORD record
ord-bbb81bc9d1e0498b818b83e991506bd4
Source dataset
uspto-grants-1988_03
Patent number
US04730067

Reaction notes

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