1,3-Propanediol, 2,2-bis(azidomethyl)- → HCID 13592266, compound

HRID 568996Notes

Reaction equation

HRID 568996 reaction equation
[CH2:1]([C:19]([CH3:21])=[O:20])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[OH:22][CH2:23][C:24]([CH2:33]O)([CH2:29][N:30]=[N+:31]=[N-:32])[CH2:25][N:26]=[N+:27]=[N-:28].N(CC1(CN=[N+]=[N-])COC(CCCCCCCCCC)(C)OC1)=[N+]=[N-]>>[N:30]([CH2:29][C:24]1([CH2:25][N:26]=[N+:27]=[N-:28])[CH2:23][O:22][C:19]([CH3:21])([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])[O:20][CH2:33]1)=[N+:31]=[N-:32]

Participants

4

Reactant 3

HCID 121709631,3-Propanediol, 2,2-bis(azidomethyl)-HCID 135922652-IcosanoneHCID 13592267HCID 13592267, compound2×

Product 1

HCID 13592266HCID 13592266, compound

Procedure

The following compound was prepared analogously as described in Example 9, starting from methyl octadecyl ketone and compound 1. 5,5-Bis-(azidomethyl)-2-decyl-2-methyl-1,3-dioxane (compound 17).

Workup

  1. customThe following compound was prepared analogously

Sources & evidence

ORD record
ord-fa5fb2052c2f4a41aa626a50b728b9c0
Source dataset
uspto-grants-1988_03
Patent number
US04730069

Reaction notes

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