Nitric Acid → HCID 13315132, compound

HRID 569036Notes

Reaction equation

HRID 569036 reaction equation
[CH3:1][S:2][C:3]1[N:4]=[CH:5][C:6]2[NH:7][C:8]3[C:13]([C:14]=2[CH:15]=1)=[CH:12][CH:11]=[CH:10][CH:9]=3.[N+:16]([O-])([OH:18])=[O:17]>O>[N+:16]([C:11]1[CH:12]=[C:13]2[C:8](=[CH:9][CH:10]=1)[NH:7][C:6]1[CH:5]=[N:4][C:3]([S:2][CH3:1])=[CH:15][C:14]2=1)([O-:18])=[O:17]

Participants

4

Reactant 2

HCID 944Nitric AcidHCID 13315131HCID 13315131, compound

Product 1

HCID 13315132HCID 13315132, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

970 mg of 3-methylthio-β-carboline are stirred for 4 hours at room temperature with 60 ml of 65% nitric acid. After introduction of the preparation into water, it is suctioned off and dried. 950 mg of 6-nitro-3-methylthio-β-carboline with a >250° C. melting point are obtained.

Workup

  1. customdried
  2. customwith a >250° C.
  3. customare obtained

Sources & evidence

ORD record
ord-b60dc2a8e06e491d86f41f472b01bbda
Source dataset
uspto-grants-1988_03
Patent number
US04731358

Reaction notes

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