Nitroethane → HCID 54489179, compound

HRID 569090Notes

Reaction equation

HRID 569090 reaction equation
C(OC(C1N=CC2NC3C(C=2C=1C)=C(C=O)C=CC=3)=O)C.[N+](CC)([O-])=O.[CH2:27]([O:29][C:30]([C:32]1[N:33]=[CH:34][C:35]2[NH:36][C:37]3[C:42]([C:43]=2[C:44]=1[CH3:45])=[C:41]([CH:46]=[C:47]([N+:49]([O-])=O)[CH3:48])[CH:40]=[CH:39][CH:38]=3)=[O:31])[CH3:28]>>[CH2:27]([O:29][C:30]([C:32]1[N:33]=[CH:34][C:35]2[NH:36][C:37]3[C:42]([C:43]=2[C:44]=1[CH3:45])=[C:41]([CH2:46][CH:47]([NH2:49])[CH3:48])[CH:40]=[CH:39][CH:38]=3)=[O:31])[CH3:28]

Participants

4

Reactant 3

HCID 6587NitroethaneHCID 54371401HCID 54371401, compoundHCID 54456541HCID 54456541, compound

Product 1

HCID 54489179HCID 54489179, compound

Procedure

The production takes places analogously to example 9 by condensation of 5-formyl-4-methyl-beta-carboline-3-carboxylic acid ethyl ester with nitroethane and hydrogenation of the resulting 4-methyl-5-(2-nitropropenyl)-beta-carboline-3-carboxylic acid ethyl ester.

Sources & evidence

ORD record
ord-53dcf68ea3eb4d2d9a1b095195bc16aa
Source dataset
uspto-grants-1988_03
Patent number
US04731365

Reaction notes

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