HCID 13561831, compound → HCID 13561832, compound

HRID 569696Notes

Reaction equation

HRID 569696 reaction equation
[C:1]([C:3]([C:20]#[N:21])=[CH:4][NH:5][NH:6][C:7]1[C:12]([Cl:13])=[CH:11][C:10]([S:14][C:15]([F:18])([F:17])[F:16])=[CH:9][C:8]=1[Cl:19])#[N:2]>C(OCCO)C>[NH2:2][C:1]1[N:6]([C:7]2[C:12]([Cl:13])=[CH:11][C:10]([S:14][C:15]([F:16])([F:17])[F:18])=[CH:9][C:8]=2[Cl:19])[N:5]=[CH:4][C:3]=1[C:20]#[N:21]

Participants

3

Reactant 1

HCID 13561831HCID 13561831, compound

Product 1

HCID 13561832HCID 13561832, compoundYield 70%

Reagents, catalysts & solvents 1

HCID 8076Glycol monoethyl etherSolvent

Procedure

14.1 g (0.04 mol) of 1-(2,2-dicyanoethen-1-yl)-2-(2,6-dichloro-4-trifluoromethylthio-phenyl)-hydrazine in 30 ml of ethylene glycol monoethyl ether are heated under reflux for 2 hours. Active carbon is added to the hot solution, the mixture is filtered and the filtrate is diluted with 60 ml of water. This precipitate which separtes out is filtered off under suction and dried. 9.8 g (70% of theory) of 5-amino-4-cyano-1-(2,6-dichloro-4-trifluoromethylthiophenyl)-pyrazole of melting point 185° C. to 187° C. are obtained. ##STR135##

Workup

  1. temperatureunder reflux for 2 hours
  2. additionActive carbon is added to the hot solution
  3. filtrationthe mixture is filtered
  4. additionthe filtrate is diluted with 60 ml of water
  5. filtrationThis precipitate which separtes out is filtered off under suction
  6. customdried

Sources & evidence

ORD record
ord-eaeae76600c44b7980988f3b9ae4c3ed
Source dataset
uspto-grants-1988_03
Patent number
US04734122

Reaction notes

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